Kinetic Reactions Card Syntax (-R)
Character string (e.g., van Genuchten, porosity, m^3/s, Roe Superbee)
Integer (no alpha characters, special characters, or punctuation) (e.g., 1, 32, 195634)
Real (decimal points and exponential notation allowed) (e.g., 0, 0.0, 1.e-12, 1.E+3, 2.345)
Keyword (exact formatting required) (e.g., file, ~Solution Control Card, binary file)
Card Title
~Kinetic Reactions Card
Number of Kinetic Reactions,
Select Kinetic Reaction Type
Kinetic Reaction Name,TST,Mineral Species Name,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), Equilibrium Constant Coefficient a,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name, TST toward reactants,Mineral Species Name ,...
...Number of Reactants,
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), Equilibrium Constant Coefficient a,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,TST toward products,Mineral Species Name,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), Equilibrium Constant Coefficient a,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name, TST w/pH,Mineral Species Name,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), pH Dependency Exponent,Equilibrium Constant Coefficient a,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name, TST w/pH toward reactants,Mineral Species Name ,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), pH Dependency Exponent,Equilibrium Constant Coefficient a,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name, TST w/pH toward products,Mineral Species Name ,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), pH Dependency Exponent,Equilibrium Constant Coefficient a,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name, Schaef TST w/pH toward reactants,Mineral Species Name ,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,Number of Products,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), pH Dependency Exponent,Equilibrium Constant Coefficient a,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name, Schaef TST w/pH toward products,Mineral Species Name ,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), Equilibrium Constant Coefficient a,pH Dependency Exponent,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name, TST w/pH w/glass toward reactants,Mineral Species Name ,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), pH Dependency Exponent,Equilibrium Constant Coefficient a,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Note that this is a specialized Kinetic Reaction Type for low-level vitrified waste that only permits dissolution. The rate of dissolution is dependent on pH and silica concentrations.
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TST with Ion Exchange, pH and Time Dependency Toward Reactants
Kinetic Reaction Name, TST w/iex pH w/Time Dependency Toward Reactants,Mineral Species Name ,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Ion Exchange Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), pH Dependency Exponent,Kinetic Reaction Time Exponent,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Note that this is a specialized Kinetic Reaction Type for low-level vitrified waste that only permits dissolution. The rate of dissolution is dependent on pH and silica concentrations.
Kinetic Reaction Name, Constant rate TST,Mineral Species Name ,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name, Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name, Product Species Stoichiometric Coefficient,...
...Reaction Rate at the Reference Temperature,Units(mol/m^2 s),Activation Energy,Units(J/mol),Reference Temperature,Units(C), pH Dependency Exponent,Equilibrium Constant Coefficient a,Equilibrium Constant Coefficient b,Equilibrium Constant Coefficient c,Equilibrium Constant Coefficient d, Equilibrium Constant Coefficient e,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Note that this is a specialized Kinetic Reaction Type for low-level vitrified waste that only permits dissolution. The rate of dissolution is dependent on pH and silica concentrations.
Kinetic Reaction Name,forward-backward,Mineral Species Name,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name,Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name,Product Species Stoichiometric Coefficient,...
...Forward Reaction Rate,Units(1/s),Backward Reaction Rate,Units(1/s),
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Valochi Monod,3,Donor Species Name,Donor Stoichiometric Coefficient,Acceptor Species Name,Acceptor Stoichiometric Coefficient,Biomass Species Name,Biomass Stoichiometric Coefficient,0,Half-Saturation Constant for Donor, Units(mol/kg),Half-Saturation Constant for Acceptor,Units(mol/kg),Maximum Specific Rate of Substrate Utilization,Units(1/s),
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Valochi Biomass,3,Donor Species Name,Donor Stochiometric Coefficient,Acceptor Species Name,Acceptor Stochiometric Coefficient,Biomass Species Name,Biomass Stochiometric Coefficient,Half-Saturation Constant for Donor,Units(mol/kg),Half-Saturation Constant for Acceptor,Units(mol/kg),Maximum Specific Rate of Substrate Utilization,Units(1/s),Microbial Yield Coefficient,Microbial Decay Coefficient,Units(1/s),
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Valochi Sorption,1,Aqueous Species Name,1,1.0,Sorbed Species Name,1.0,Mass Transfer Coefficient,Units(1/s),Distribution Coefficient,Units(m^3 /kg),
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Langmuir Sorption,Kinetic Reaction Type ,1,Reactant Species Name,Reactant Species Stoichiometric Coefficient,1,Product Species Name,Product Species Stoichiometric Coefficient,Forward Mass Transfer Coefficient,Units (1/s),Backward Mass Transfer Coefficient,Units(1/s),Maximum Sorbed Concentration,Units(mol/kg),
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Monod,Kinetic Reaction Type,Number of Reactants,Biomass,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name,...
...Half Saturation Constant for Donor,Units(mol/kg), Maximum Specific Rate of Substrate Utility, Units(1/s),
Number of reactants must be greater than 1.
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Single Monod,Kinetic Reaction Type,2,Reactant Species Name,Reactant Species Stoichiometric Coefficient,0,Half Saturation Constant for Donor,Units(mol/kg),Maximum Specific Rate of Substrate Utility,Units (1/s),
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Dual Monod,1,Aqueous Species Name,2,Reactant Species Name,Reactant Species Stoichiometric Coefficient,0,Half Saturation Constant for Donor,Units(mol/kg),Half Saturation Constant for Acceptor, Units(mol/kg),Maximum Specific Rate of Substrate Utility,Units (1/s),
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Biomass,Number of Reactants,Biomass,...
List all reactants
...Reactant Species Name,...
...Half Saturation Constant, Units(mol/kg),Maximum Specific Rate of Substrate Utility,Units(1/s),Biomass Yield Coefficient,Microbial Decay Coefficient,Units (1/s),
Number of reactants must be greater than 1.
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Liu Lognormal,Kinetic Reaction Type,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name,Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name,Product Species Stoichiometric Coefficient,...
...Rate constant,Units (1/s),Kinetic Site Density,Units(mol/g),Pore Ratio of Immobile Pore to Mobile Pore,Log K of the First Sorbed Species on the Site,LogK of the Second Sorbed Species on the Site,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
Kinetic Reaction Name,Liu DualDomain,Kinetic Reaction Type,Number of Reactants,...
Repeat for number of reactants in kinetic reaction
...Reactant Species Name,Reactant Species Stoichiometric Coefficient,...
...Number of Products,...
Repeat for number of products in kinetic reaction
...Product Species Name,Product Species Stoichiometric Coefficient,...
...Rate constant,Units,Pore Ratio of Immobile Pore to Mobile Pore,
Any parameter value or coefficient can be replaced with an external file using the following syntax:
,file:filename for parameter,
or for binary files:
filename for parameter,
External Files
File names must be all lower case. Files must contain text data unless specified as binary in which case they must contain binary data created with the same FORTRAN compiler used to compile STOMP. Files contain parameter values for every grid-cell, ordered according to the IJK indexing scheme.
RETURNs are allowed at any point on the input line
ECKEChem Input Cards
- Conservation Equations Card
- Equilibrium Equations Card
- Equilibrium Reactions Card
- Gas Species Card
- Kinetic Equations Card
- Kinetic Reactions Card
- Lithology Card
- Solid Species Card
- Species Link Card
- Aqueous Species Card
- Exchanged Species Card
- Plot File Species Variables
- Reference Node Species Variables